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Item HD molecules at high redshift: A low astration factor of deuterium in a solar-metallicity DLA system at z=2.418(2008-08) Noterdaeme, P.; Srianand, R.We present the detection of deuterated molecular hydrogen (HD) in the remote Universe in a damped Lyman-α cloud at zabs = 2.418 toward the quasar SDSS J143912.04+111740.5. This is a unique system in which H2 and CO molecules are also detected. The chemical enrichment of this gas derived from Zn ii and S ii is as high as in the Sun. We measure N(HD)/2N(H2) = 1.5+0.6 −0.4 × 10−5, which is significantly higher than the same ratio measured in the Galaxy and close to the primordial D/H ratio estimated from the WMAP constraint on the baryonic matter density (Ωb). This indicates a low astration factor of deuterium that contrasts with the unusually high chemical enrichment of the gas. This can be interpreted as the consequence of an intense infall of primordial gas onto the associated galaxy. Detection of HD molecules at high-z also opens the possibility to obtain an independent constraint on the cosmological-time variability of , the proton-to-electron mass ratio.Item First detection of CO in a high-redshift damped Lyman - Alpha system(2008-04) Srianand, R.We present the first detection of carbon monoxide (CO) in a damped Lyman-α system (DLA) at zabs =2.41837 toward SDSS J143912.04+111740.5. We also detected H2 and HD molecules. The measured total column densities (in log units) of H i, H2, and CO are 20.10±0.10, 19.38±0.10, and 13.89±0.02, respectively. The molecular fraction, f = 2N(H2)/(N(H i)+2N(H2)) = 0.27+0.10 −0.08, is the highest among all known DLAs. The abundances relative to solar of S, Zn, Si, and Fe are −0.03±0.12, +0.16±0.11, −0.86±0.11, and −1.32±0.11, respectively, indicating a high metal enrichment and a depletion pattern onto dust-grains similar to the cold ISM of our Galaxy. The measured N(CO)/N(H2) = 3×10−6 is much less than the conventional CO/H2 ratio used to convert the CO emission into gaseous mass but is consistent with what is measured along translucent sightlines in the Galaxy. The CO rotational excitation temperatures are higher than those measured in our Galactic ISM for similar kinetic temperature and density. Using the C i fine structure absorption lines, we show that this is a consequence of the excitation being dominated by radiative pumping by the cosmic microwave background radiation (CMBR). From the CO excitation temperatures, we derive TCMBR = 9.15±0.72 K, while 9.315±0.007 K is expected from the hot big-bang theory. This is the most precise high-redshift measurement of TCMBR and the first confirmation of the theory using molecular transitions at high redshift.Item Detection of 21-cm, H2 and Deuterium absorption at z>3 along the line-of-sight to J1337+3152(2010-02-24) Srianand, R.; Gupta, Neeraj; Petitjean, Patrick; et al.We report the detection of 21-cm and molecular hydrogen absorption lines in the same damped Lyman-α system (with log N(H i)=21.36±0.10) at zabs=3.17447 towards SDSS J133724.69+315254.55 (zem ∼3.174). We estimate the spin temperature of the gas to be, TS = 600+222−159 K, intermediate between the expected values for cold and warm neutral media. This suggests that the H i absorption originates from a mixture of different phases. The total molecular fraction is low, fH2=10−7, and H2 rotational level populations are not in equilibrium. The average abundance of the α- elements is, [S/H]=−1.45 ± 0.22. Nitrogen and iron are found underabundant with respect to α-elements by ∼1.0 dex and ∼0.5 dex respectively. Using photoionization models we conclude that the gas, of mean density, nH ∼2 cm−3, is located more than 270 kpc away from the QSO. While the position of 21-cm absorption line coincides with the H2 velocity profile, its centroid is shifted by ∼2.7±1.0 km s−1 with respect to the redshift measured from the H2 lines. However, the position of the strongest metal absorption component matches the position of the 21-cm absorption line within 0.5 km s−1. From this, we constrain the variation of the combination of fundamental constants x = α2Gp/µ, ∆x/x = −(1.7±1.7)×10−6. This system is unique as we can at the same time have an independent constrain on µ using H2 lines. However, as the H2 column density is low, only Werner band absorption lines are seen and, unfortunately, the range of sensitivity coefficients is too narrow to provide a stringent constraint: ∆µ/µ ≤ 4.0 × 10−4. The Ultraviolet and Visual Echelle Spectrograph (UVES) spectrum reveals another DLA at zabs= 3.16768 with log N(H i) = 20.41±0.15 and low metallicity, [Si/H] = −2.68 ± 0.11, in which [O/C] ∼ 0.18 ± 0.18 and [O/Si] ∼ 0. This shows that even in the very early stages of chemical evolution, the carbon or silicon to oxygen ratios can be close to solar. Using Voigt profile fitting we derive log(N(D i)/N(H i)) = −(4.93 ± 0.15) in this system. This is a factor of two smaller than the value expected from the best fitted value of Ωb from theWilkinson Microwave Anisotropy Probe (WMAP) 5 year data. This confirms the presence of astration of deuterium even at very low metallicity.