Fox, Andrew J.Petitjean, PatrickLedoux, C.et al.2012-03-062012-03-062007-08-22http://hdl.handle.net/11007/650We present a VLT/UVES spectrum of a proximate sub-damped Lyman-α (sub-DLA) system at zabs = 2.65618 toward the quasar Q0331-4505 (zqso = 2.6785±0.0030). Absorption lines of O I, Si II,Si III, Si IV, C II, C III, C IV, Fe II, Al II, and O VI are seen in the sub-DLA, which has a neutral hydrogen column density logNHI = 19.82 ± 0.05. The absorber is at a velocity of 1 820 ± 250 kms−1 from the quasar; however, its low metallicity [O/H]=−1.64 ± 0.07, lack of partial coverage, lack of temporal variations between observations taken in 2003 and 2006, and non-detection of N V imply the absorber is not a genuine intrinsic system. By measuring the O VI column density and assuming equal metallicities in the neutral and ionized gas, we determine the column density of hot ionized hydrogen in this sub-DLA, and in two other sub-DLAs with O VI drawn from the literature. Coupling this with determinations of the typical amount of warm ionized hydrogen in sub-DLAs, we confirm that sub-DLAs are a more important metal reservoir than DLAs, in total comprising at least 6–22% of the metal budget at z ≈ 2.5.enIntergalactic medium – quasarsAbsorption lines – galaxiesHalos – galaxiesHigh- redshiftArticle